A NADPH substitute for selective photo-initiation of reductive bioprocesses via two-photon induced electron transfer.

نویسندگان

  • Anne-Claire Robin
  • Said Gmouh
  • Olivier Mongin
  • Viatcheslav Jouikov
  • Martinus H V Werts
  • Clément Gautier
  • Anny Slama-Schwok
  • Mireille Blanchard-Desce
چکیده

A NADPH substitute where the nicotinamide moiety is replaced by a chromophoric unit having much larger two-photon absorption cross-section and able to transfer electrons to flavins only upon excitation is described as an effective two-photon nanotrigger for selective photo-activation of electron transfer in bioreductive processes.

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عنوان ژورنال:
  • Chemical communications

دوره 13  شماره 

صفحات  -

تاریخ انتشار 2007